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CCZ Castillo Copper Limited

0.25
0.00 (0.00%)
24 Apr 2024 - Closed
Delayed by 15 minutes
Share Name Share Symbol Market Type Share ISIN Share Description
Castillo Copper Limited LSE:CCZ London Ordinary Share AU000000CCZ2 ORD NPV (DI)
  Price Change % Change Share Price Bid Price Offer Price High Price Low Price Open Price Shares Traded Last Trade
  0.00 0.00% 0.25 0.20 0.30 0.287 0.25 0.25 0.00 08:00:21
Industry Sector Turnover Profit EPS - Basic PE Ratio Market Cap
Copper Ores 0 -6.94M -0.0053 0.00 0

Castillo Copper Limited NWQ Copper Project's development targets (4719N)

23/01/2023 7:00am

UK Regulatory


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RNS Number : 4719N

Castillo Copper Limited

23 January 2023

23 January 2023

CASTILLO COPPER LIMITED

("Castillo", or the "Company")

NWQ Copper Project's development targets

Castillo Copper Limited (LSE and ASX: CCZ), a base metal explorer primarily focused on copper across Australia and Zambia, announces that following a review of prospects within the NWQ Copper Project (Appendix A), has authorised the geology team to visit several prospects - including Big One, Arya and Valparaisa - during 1H 2023 to identify new targets for test-drilling.

HIGHLIGHTS:

-- Initial focus will be on the Big One, which has an inferred Mineral Resource Estimate (MRE) of 2.1Mt @ 1.1% Cu for 21,886kt(1) copper metal post-two drilling campaigns across 2020-21:

o Factoring in a large conductor north of the line of lode, plus reconciling available geophysics and geochemical data, Castillo's geological consultant has set an Exploration Target that ranges from 2-6Mt @ 0.6-1% Cu for 12-60kt copper metal*

-- The Valparaisa Prospect comprises copper mineralisation across two horizons over a 6km strike event, with the interaction of two intersecting faults suggesting a structurally controlled copper system that can potentially be drill-tested(2)

-- At the Arya Prospect, there is a significant magnetic anomaly, south of a known graphite system(3) (test drilled in late 2021), that shows potential to be a primary source of copper mineralisation

-- Meanwhile, final drill and auger assays, which are still pending, should define the potential scale of the rare earth element discovery at the BHA Project's East Zone

Dr Dennis Jensen, Managing Director of Castillo Copper, said: "With the macro-outlook for copper remaining upbeat, the Board has authorised the geology team to visit several prospects to identify new targets to test-drill. Key areas of focus include increasing the grade and confidence in the current MRE at Big One and the magnetic anomaly at the Arya Prospect. Given the large size of the NWQ Copper Project, the Board remains open to aligning with a strategic partner to further advance development work."

* Cautionary Statement: It should be noted that the Exploration Target tonnage range quoted above are conceptual in nature and there has been insufficient exploration to define a copper resource. Although a preliminary analysis was undertaken, insufficient data exists to confidently correlate mineralised horizons within the Exploration Target area. It is uncertain whether further exploration may lead to the reporting of a JORC-standard resource, however, there is some evidence to support the current exploration tonnage calculations, and the sufficient mineralised thicknesses interpreted from historical drilling to warrant further investigation in some areas.

NWQ Copper Project - Site Visit

A summary of salient points from the review for the three prospects highlighted follows:

Big One

Whilst some areas around Big One were drill-tested in the 2020-21 drilling campaigns, much of the area remains under-explored which highlights the exploration potential.

Utilising information from Castillo's drilling campaigns, complemented with historical data, Castillo's geological consultant compiled an extensive database, built a block model, and produced a maiden 2012 JORC Inferred MRE at 2.1Mt @ 1.1% Cu for 21,886kt copper metal(1) (Figure 1).

FIGURE 1 : MINERAL RESOURCE TONNAGES BIG ONE COPPER MINE

 
 Tenure         Ore         Depth           Specific    Inferred   Indicated   Copper   Silver   Contained   Contained 
  Name           Type        (m)             Gravity     (Mt)       (Mt)        Grade    Grade    Copper      Silver 
                                             (kg/m(3)                           %        g/t      (t)         (kg) 
                                             ) 
               ==========  ==============  ==========  =========  ==========  =======  =======  ========== 
                            At 
 Mine Dumps     Oxidised    surface/ROM     2.55        0          0.007       1.2      4.0      86          29.6 
               ==========  ==============  ==========  =========  ==========  =======  =======  ==========  ========== 
 Mine Insitu    Oxidised    2-70            2.65        1.7        0           1.0      1.1      17,000      1,870 
               ==========  ==============  ==========  =========  ==========  =======  =======  ==========  ========== 
 Mine Insitu    Fresh       70-120          2.75        0.4        0           1.2      1.4      4,800       560 
               ==========  ==============  ==========  =========  ==========  =======  =======  ==========  ========== 
 Sub-Totals                                             2.1        0.007                         21,886      2,459.6 
                           ==============  ==========  =========  ==========  =======  =======  ==========  ========== 
 

Note: No measured resources estimated

Source: CCZ geology team

Building on this work, the geology team believe further drilling is warranted along the known orebody to the east, north and downdip as it is not fully defined. Specifically, the geology team believe a well-designed drilling campaign - focussing on diamond coring - has the potential to materially increase the grade and confidence in the current MRE, as the orebody is open to the east and downdip.

In addition, an Exploration Target* (to the standard of Clause 17 of the 2012 JORC Code) has been estimated utilising the following information:

   --    the MRE plus some areas proximal to and downdip to the main resource shell; and 
   --    available geophysics and surface sampling data. 

The Exploration Target's* mid-range is 4Mt @ 0.6-1.0% Cu, with the low at 2Mt and high at 6Mt - refer to Figures 2 and 3. It should be explained that this is an enlarged range of tonnage compared to the MRE due a new wireframe model extended along the entire line of lode.

* Cautionary Statement: It should be noted that the Exploration Target tonnage range quoted above are conceptual in nature and there has been insufficient exploration to define a copper resource. Although a preliminary analysis was undertaken, insufficient data exists to confidently correlate mineralised horizons within the Exploration Target area. It is uncertain whether further exploration may lead to the reporting of a JORC-standard resource however there is some evidence to support the current exploration tonnage calculations, and the sufficient mineralised thicknesses interpreted from historical drilling to warrant further investigation in some areas.

FIGURE 2: BIG ONE - EXPLORATION TARGET *

 
  Target    Strike    Strike    Width   Width       Depth            Depth        Density    Density 
             Length    Length    (m)     (m)     below surface    below surface    (t/m(3)    (t/m(3) 
              (m)       (m)                           (m)              (m)            )          ) 
 Ranges       Low      High      Low    High         Low              High          Low        High 
           ========  ========  ======  ======  ===============  ===============  =========  ========= 
 Big One      600      1,550      4      14           10              190           2.65       2.80 
           ========  ========  ======  ======  ===============  ===============  =========  ========= 
 

Note: Mid-points as follows - Strike length (1,550m); Width (9m); Depth below surface (100m); Density (2.725t/m3)

Source: CCZ geology team

FIGURE 3: BIG ONE - EXPLORATION TARGET FOR COPPER *

 
  Target    Tonnage   Tonnage   Grade (%)   Grade   Contained   Contained 
              (Mt)      (Mt)                 (%)      Cu (t)      Cu (t) 
 Ranges       Low      High        Low      High       Low        High 
           ========  ========  ==========  ======  ==========  ========== 
 Big One      2.0       6.0        0.6       1.0     12,000      60,000 
           ========  ========  ==========  ======  ==========  ========== 
 

Note :

   1.        Mid-points as follows - Tonnage (4Mt); Grade (0.8%); Contained copper (32,000t) 
   2.        Volume and mass are exclusive of the Big One Copper Mine's Inferred resource shell. 

3. Where quoted, it should be noted that where Exploration Target tonnages are estimated in this ASX Release, they are considered non-JORC (Clause 17 Exploration Results) and are conceptual in nature. There has been insufficient exploration to define a Mineral Resource and that it is uncertain if further exploration will result in the determination of a Mineral Resource.

   4.        At 0.5% Cu cut-off. 

Source: CCZ geology team

* Cautionary Statement: It should be noted that the Exploration Target tonnage range quoted above are conceptual in nature and there has been insufficient exploration to define a copper resource. Although a preliminary analysis was undertaken, insufficient data exists to confidently correlate mineralised horizons within the Exploration Target area. It is uncertain whether further exploration may lead to the reporting of a JORC-standard resource however there is some evidence to support the current exploration tonnage calculations, and the sufficient mineralised thicknesses interpreted from historical drilling to warrant further investigation in some areas.

Valparaisa Prospect

The Valparaisa Prospect comprises copper mineralisation in two horizons - termed the "upper and lower copper beds" - within the Middle Gunpowder Creek Formation over a 6km strike length (Figure 4). Compared with the 'upper bed' the 'lower bed' has the stronger outcrop and more copper staining(2) .

Previous explorers, including BHP, undertook rock-chip sampling which returned high-grade assay results up to 2,530ppm Cu, demonstrating prospectivity at surface for copper mineralisation(2) . Interestingly, the surface anomalism aligns with the interaction of two intersecting faults - Mt Gordon (SW-NE - links to Mt Mammoth Deposit) and Valparaisa (SSE-NNW).

Reconciling and interpreting the foregoing facts has postulated that there is a structurally controlled copper system at the Valparaisa Prospect.

FIGURE 4: VALPARAISA PROSPECT - SOLID GEOLOGY, ROCK CHIPS & DRILLHOLES

Source: CCZ geology team

In terms of identifying potential targets for closer scrutiny, a key positive was identifying the Whitworth Quartzite rock formation within the Valparaisa fault. This is significant as it hosts copper sulphide mineralisation within the Mt Gordon fault at the Mt Mammoth Deposit. Reconciling this against overlaid magnetic imagery, enables several target areas for structurally controlled copper and supergene ore mineralisation to be generated (Figure 5).

FIGURE 5: STRUCTURALLY CONTROLLED AND SUPERGENE TARGETS

Source: CCZ geology team

Arya Prospect

A limited drilling campaign in late 2021, designed to test several large airborne electro-magnetic and ground resistivity anomalies, confirmed a low-grade graphite system that won't be further explored (refer Appendix B for assay results).

However, a sizeable magnetic anomaly - south of the known electro-magnetic anomalies - is interpreted to be associated with known surface copper and to a lesser degree silver mineralisation. A key focus of the site visit is to determine if this should be drill-tested as it may be a primary source of base metal mineralisation at the Arya Prospect.

In terms of regional geology, the Arya Prospect is located in the Western Mt Isa Succession, within a structurally deformed and copper anomalous district that hosts the Capricorn Copper Mine, Mt Oxide Mine and the Ladie Annie Mine. These are hosted within units of the upper Myally sub-group to lower McNamara Group, while the Arya Prospect is hosted within the Surprise Creek formation (Figure 6).

FIGURE 6: STRATIGRAPHIC COLUMN

Source : Smith (2019) - reference 4

In terms of local geology, the Arya Prospect is located within the Surprise Creek Formation unit (Prd), with several results from rock-chip sampling indicative of a structural system for anomalous copper values (Figure 7). Moreover, the Arya Prospect is proximal to an east to north-east trending fault that offsets the Surprise Creek unit (Prd) from lower units near the base of the Surprise Creek Formation, and Myally Sub-Group units, including quartzites, and sandstones.

FIGURE 7: COPPER GEOCHEMISTRY ON QUEENSLAND GOVT GEOLOGICAL MAP

Source : Smith (2019) - reference 4

Interpreting these findings, suggests probable mineralisation styles include:

-- Supergene mineralisation forming at the surface along the fault, fault breccia, and the Surprise Creek Formation (PLrd) rock unit.

-- Epigenetic replacement mineralisation for Cu (with minor components of other base metals and gold) from replacement carbonate mineralisation, particularly the Surprise Creek Formation.

-- Skarn mineralisation for Cu-Au and/or Zn-Pb-Cu from replacement carbonate mineralisation, particularly the Surprised Creek Formation.

-- Sulphide mineralisation within breccia zones, along stress dilation fractures, emplaced within pore spaces, voids, or in other rock fractures; and/or dykes.

Main ore minerals observed comprise:

-- Malachite and chrysocolla along foliation, in brecciated/strongly haematitic sedimentary rocks.

   --    Quartzite/rhyolite with chrysocolla on joint surfaces and fractures, circa 3-5% Cu. 
   --    Malachite and azurite on joint planes in porous sandstone. 

For further information, please contact:

 
Castillo Copper Limited                               +61 8 6558 0886 
Dr Dennis Jensen (Australia), Managing Director 
 Gerrard Hall (UK), Chairman 
 
SI Capital Limited (Financial Adviser and Corporate 
 Broker)                                              +44 (0)1483 413500 
Nick Emerson 
 
Gracechurch Group (Financial PR)                      +44 (0)20 4582 3500 
Harry Chathli, Alexis Gore, Henry Gamble 
 

About Castillo Copper

Castillo Copper Limited is an Australian-based explorer primarily focused on copper across Australia and Zambia. The group is embarking on a strategic transformation to morph into a mid-tier copper group underpinned by its core projects:

-- A large footprint in the Mt Isa copper-belt district, north-west Queensland, which delivers significant exploration upside through having several high-grade targets and a sizeable untested anomaly within its boundaries in a copper-rich region.

-- Four high-quality prospective assets across Zambia's copper-belt which is the second largest copper producer in Africa.

-- A large tenure footprint proximal to Broken Hill's world-class deposit that is prospective for zinc-silver-lead-copper-gold and platinoids.

-- Cangai Copper Mine in northern New South Wales, which is one of Australia's highest grading historic copper mines.

The group is listed on the LSE and ASX under the ticker "CCZ."

Competent Person's Statement

The information in this report that relates to Exploration Results and Mineral Resource Estimates for "BHA Project, East Zone" is based on information compiled or reviewed by Mr Mark Biggs. Mr Biggs is a director of ROM Resources, a company which is a shareholder of Castillo Copper Limited. ROM Resources provides ad hoc geological consultancy services to Castillo Copper Limited. Mr Biggs is a member of the Australian Institute of Mining and Metallurgy (member #107188) and has sufficient experience of relevance to the styles of mineralisation and types of deposits under consideration, and to the activities undertaken, to qualify as a Competent Person as defined in the 2012 Edition of the Joint Ore Reserves Committee (JORC) Australasian Code for Reporting of Exploration Results, and Mineral Resources. Mr Biggs holds an AusIMM Online Course Certificate in 2012 JORC Code Reporting. Mr Biggs also consents to the inclusion in this report of the matters based on information in the form and context in which it appears.

References

   1)        CCZ ASX Release - 28 February 2022 
   2)        CCZ ASX Release - 7 September 2020 
   3)        CCZ ASX Release - 10 August 2021 & 17 November 2021; 28 January 2022 

4) Smith P., 2019, Ayra Mt Oxide prospect, unpublished report by Yoda Consulting Pty Ltd to Castillo Copper Limited, Apr 2019, 15pp.

APPIX A: NWQ COPPER PROJECT

FIGURE A1: PROSPECTS WITHIN NWQ COPPER PROSPECT

Source: CCZ geology team

APPIX B: ARYA PROSPECT - METALLURGICAL TESTS

Background petrographic description

One composite sample from drill-hole AR_002RC, sized into 7 fractions, was submitted for optical investigation, with the main aim of characterising the presence and mode of occurrence of graphite (Schulz and others 2022; refer to Appendix C for reference list).

Polished blocks were prepared for all size fractions, and these were examined using a petrographic microscope (reflected light). Further, representative splits of the +800 um and +500 um fractions were examined using a stereo microscope.

Reflected light images of selected fields of the polished blocks (all size fractions) and stereo-microscope images of the unmounted +800 um and +500 um fractions were included in the metallurgical report (refer Appendix C: Schulz and others 2022). Figure AB-1 illustrates the nature of mica and sulphide inclusions in the sized schist chips.

FIGURE AB-1: PHOTOMICROGRAPH - SCHIST PARTICLES W/MICA & SULPHIDE INCLUSIONS

Source: ALS Perth

The presence of graphite was confirmed by the optical investigation. With the chosen settings, graphite particles are identified as creamy white, elongated particles under reflected light. The graphite flakes range in size from a few um (not positively identifiable by the optical investigation) to about 50 um in length.

They occur as fine-grained flakes within larger, silicate-rich particles (see Figure AB-2 for an example of the graphite grains).

FIGURE AB-2: GRAPHITE AND SULPHIDE INCLUSIONS WITHIN SCHIST FRAGMENTS

Source: ALS Perth

Graphite sizing and optical analysis

The composite sample supplied to ALS Perth's laboratory was made up as follows:

-- AR_002RC: 17m - samples CCZ03231 (73m) to CCZ03247 (90m) from the coarsest fraction saved. This graphite prospect is low grade, but there are large thicknesses (e.g., 56m @ 1.35% TGC and 0.25 g/t Ag in one hole). The field association of the Ag and its relationship to graphite has yet to be resolved. The sulphur and vanadium reporting from assays over the graphite horizons are low.

-- The sizing of the supplied RC chips and subsequent testing and optical analysis is given by Figure AB-3 below. No further sizing was conducted on the graphite component.

FIGURE AB-3: AR_002RC SIZING AND OPTICAL ANALYSIS

Note:

   1.        This sizing distribution is for the whole RC chip composite, not the graphite component. 
   2.        No graphite grains above 50um in length were detected. 

Source: ALS Perth

APPIX C: JORC CODE, 2012 EDITION - TABLE 1 AYRA DRILLING AND SURFACE ROCK CHIP SAMPLING

Section 1 Sampling Techniques and Data

(Criteria in this section apply to all succeeding sections.)

 
 Criteria       JORC Code explanation                                              Commentary 
 Sampling                                                                               Drilling 
  techniques          *    Nature and quality of sampling (e.g., cut channels,           *    Reverse Circulation samples were taken off a cyclone 
                           random chips, or specific specialised industry                     for every metre drilled, put through a three tier, 
                           standard measurement tools appropriate to the                      87.5/12.5 splitter where approximately 2.5 kg of RC 
                           minerals under investigation, such as down hole gamma              chip samples were collected for every metre drilled. 
                           sondes, or handheld XRF instruments, etc). These                   The remainder was bagged separately and stored in 
                           examples should not be taken as limiting the broad                 case additional sub sampling is required before the 
                           meaning of sampling.                                               end of the program. 
 
 
                      *    Include reference to measures taken to ensure sample          *    Samples were also composited every four metres where 
                           representivity and the appropriate calibration of any              visual inspection did not initially indicate copper 
                           measurement tools or systems used.                                 or cobalt mineralisation. All samples were collected 
                                                                                              to maximise optimal representation for each sample. 
 
                      *    Aspects of the determination of mineralisation that 
                           are Material to the Public Report.                            *    Each metre sample had an amount removed for washing 
                                                                                              and cleaning and sieving then place into metre 
                                                                                              allocated chip trays. These chips were logged on site 
                      *    In cases where 'industry standard' work has been done              by the rig geologists and those logs have been saved 
                           this would be relatively simple (e.g., 'reverse                    into a spreadsheet and stored on the Company server. 
                           circulation drilling was used to obtain 1 m samples                Any visible mineralisation, alteration or other 
                           from which 3 kg was pulverised to produce a 30 g                   salient features were recorded in the logs. 
                           charge for fire assay'). In other cases, more                      Industry-wide, acceptable, standard practices were 
                           explanation may be required, such as where there is                adhered to for the drilling and sampling of each 
                           coarse gold that has inherent sampling problems.                   metre as per the drilling and sampling Procedures set 
                           Unusual commodities or mineralisation types (e.g.,                 out before commencement of the drilling programme. 
                           submarine nodules) may warrant disclosure of detailed 
                           information. 
                                                                                        Rock Chip Sampling 
                                                                                         *    CCZ completed rock chip sampling methods over at 
                                                                                              least four (4) separate surface sampling campaigns 
                                                                                              and are described in the October and November 2021 
                                                                                              ASX Releases, a generalised description of rock chip 
                                                                                              sample collection is presented here. 
 
 
                                                                                         *    Rock Chip Samples - were collected up to 
                                                                                              approximately a 5m radius around the recorded 
                                                                                              co-ordinate location. The rock chip fragments that 
                                                                                              were collected to make up the sample included a 
                                                                                              typical fragment size that approximately ranged from 
                                                                                              2-5cm. 
 
 
                                                                                         *    Sub-sampling occurred as described in the section 
                                                                                              'Sub-sampling techniques and sample preparation' in 
                                                                                              Section 1 of the current Table 1. 
 
 
                                                                                         *    The surface sample results described in this ASX 
                                                                                              Release are suitable for the reporting 'exploration 
                                                                                              results' for mineral prospectivity, additional 
                                                                                              exploration work would have to be completed to 
                                                                                              geologically model and then estimate a mineral 
                                                                                              resource. 
               =================================================================  ================================================================= 
 Drilling 
  techniques           *    Drill type (eg core, reverse circulation, open-hole          *    Arya. Reverse Circulation, RC, and Rotary Air blast 
                            hammer, rotary air blast, auger, Bangka, sonic, etc)              (RAB) drilling techniques were utilised for all holes 
                            and details (eg core diameter, triple or standard                 drilled at the Arya Deposit. 
                            tube, depth of diamond tails, face-sampling bit or 
                            other type, whether core is oriented and if so, by 
                            what method, etc). 
               =================================================================  ================================================================= 
 Drill sample 
  recovery            *    Method of recording and assessing core and chip               *    For the 2021 program, within acceptable industry 
                           sample recoveries and results assessed.                            standard limits, all samples collected were of near 
                                                                                              equal mass and recoveries were also within acceptable 
                                                                                              limits for RC drilling and all recorded in the daily 
                      *    Measures taken to maximise sample recovery and ensure              logs. Every effort was made on site to maximise 
                           representative nature of the samples.                              recovery including cleaning out the sample trays, 
                                                                                              splitter and cyclone and ensuring that the drillers 
                                                                                              progressed at a steady constant rate for the rig to 
                      *    Whether a relationship exists between sample recovery              easily complete each metre effectively. 
                           and grade and whether sample bias may have occurred 
                           due to preferential loss/gain of fine/coarse 
                           material. 
               =================================================================  ================================================================= 
 Logging 
                       *    Whether core and chip samples have been geologically         *    Every metre drilled and sampled was logged 
                            and geotechnically logged to a level of detail to                 geologically in accordance with industry-wide 
                            support appropriate Mineral Resource estimation,                  acceptable standard for RC logging and the logging 
                            mining studies and metallurgical studies.                         was qualitative in nature with every metre logged. 
                                                                                              The 2021 program recorded visible sulphide, carbonate 
                                                                                        , 
                       *    Whether logging is qualitative or quantitative in                 and graphite concentrations and alteration minerals, 
                            nature. Core (or costean, channel, etc) photography.              such as orthoclase, epidote, chlorite, and sericite. 
 
 
                       *    The total length and percentage of the relevant 
                            intersections logged. 
               =================================================================  ================================================================= 
 Sub-sampling                                                                           Drilling 
  techniques           *    If core, whether cut or sawn and whether quarter,            *    For the 2021 program, samples with pXRF copper 
  and sample                half or all core taken. 
  preparation 
                                                                                         *    Each metre sample had an amount removed for washing 
                       *    If non-core, whether riffled, tube sampled, rotary                and cleaning and sieving then place into metre 
                            split, etc. and whether sampled wet or dry.                       allocated chip trays. These chips were logged on site 
                                                                                              by the rig geologists and those logs have been saved 
                                                                                              into a spreadsheet and stored on the Company server. 
                       *    For all sample types, the nature, quality, and                    Any visible mineralisation, alteration or other 
                            appropriateness of the sample preparation technique.              salient features were recorded in the logs. Industry 
                                                                                              wide, acceptable, standard practices were adhered to 
                                                                                              for the drilling and sampling of each metre as per 
                       *    Quality control procedures adopted for all                        the Drilling and Sampling Procedures set out before 
                            sub-sampling stages to maximise representivity of                 commencement of the drilling programme. 
                            samples. 
 
                                                                                         *    Any reporting of significant mineralised intervals 
                       *    Measures taken to ensure that the sampling is                     was on a received apparent thickness x interval 
                            representative of the in-situ material collected,                 calculation (i.e., thickness averaged). 
                            including for instance results for field 
                            duplicate/second-half sampling. 
                                                                                        Rock Chip Sampling 
                                                                                         *    All surface samples were collected dry. 
                       *    Whether sample sizes are appropriate to the grain 
                            size of the material being sampled. 
                                                                                         *    The surface sample results described in this ASX 
                                                                                              Release are suitable for the reporting 'exploration 
                                                                                              results' for mineral prospectivity, additional 
                                                                                              exploration work would have to be completed to 
                                                                                              geologically model and then estimate a mineral 
                                                                                              resource. 
               =================================================================  ================================================================= 
 Quality 
  of assay            *    The nature, quality and appropriateness of the                 *    CCZ's RC holes were assayed by an independent 
  data and                 assaying and laboratory procedures used and whether                 laboratory, ALS at Mt Isa, Townsville, or Brisbane 
  laboratory               the technique is considered partial or total.                       Australia. Methods used were as follows: 
  tests 
 
                      *    For geophysical tools, spectrometers, handheld XRF            o Gold - by method Au-AA25 30g charge (fire Assay 
                           instruments, etc, the parameters used in determining          with AAS finish). 
                           the analysis including instrument make and model,             o High gold values within oxide zone/supergene 
                           reading times, calibrations factors applied and their         zone may need further testing by method Au-SCR21. 
                           derivation, etc.                                              o Copper and 32 other - by method ME-MS61 (HF-HN03-HCL04 
                                                                                         acid digest, HCL leach and ICP-AES finish). 
                                                                                         o Over-limit copper (>10,000 ppm [0.01%]) to be 
                      *    Nature of quality control procedures adopted (eg              re assayed for copper by method Cu-OC62 (HF-HN03-HCL04 
                           standards, blanks, duplicates, external laboratory            acid digest, HCL leach and ICP-AES finish). 
                           checks) and whether acceptable levels of accuracy (ie          *    These analytical methods are considered as suitable 
                           lack of bias) and precision have been established.                  and appropriate for this type of mineralisation. 
 
 
                                                                                         For the current drilling program ALS Brisbane will 
                                                                                         analyse all samples. All elements except for gold 
                                                                                         were analysed by method ME-MS61 (41 element testing 
                                                                                         via Aqua Regia digest then ICP-AES) and with any 
                                                                                         copper assays >1%, the copper will be redone using 
                                                                                         method Cu-OG46 with ICP-AES. The gold was done 
                                                                                         by method AA25. All methods used were both suitable 
                                                                                         and appropriate for the styles of mineralisation 
                                                                                         present in the Big One Deposit at the time of sampling. 
               =================================================================  ================================================================= 
 Verification 
 of sampling          *    The verification of significant intersections by               *    All CCZ's RC hole samples have been audited for 
 and assaying              either independent or alternative company personnel.                completeness from ALS have been reviewed by two 
                                                                                               independent consultant geologists. 
 
                      *    The use of twinned holes. 
                                                                                          *    For current the rock chip sampling, Independent 
                                                                                               Laboratory assaying by ALS has confirmed, within 
                      *    Documentation of primary data, data entry procedures,               acceptable limits, the occurrences of high-grade 
                           data verification, data storage (physical and                       copper inferred from the initial XRF readings. 
                           electronic) protocols.                                              Laboratory standards and duplicates were used in 
                                                                                               accordance with standard procedures for geochemical 
                                                                                               assaying. 
                      *    Discuss any adjustment to assay data. 
               =================================================================  ================================================================= 
 Location 
  of data             *    Accuracy and quality of surveys used to locate drill          *    For rock chip samples positions were recorded by 
  points                   holes (collar and down-hole surveys), trenches, mine               handheld GPS with areas highlighting anomalies 
                           workings and other locations used in Mineral Resource              sometimes returned to for additional sampling and 
                           estimation.                                                        locations checked by handheld GPS. 
 
 
                      *    Specification of the grid system used.                        *    Locational data for the 4 drillholes completed. 
                                                                                              Collars are listed in MGA94 Zone 54 Easting (mE) and 
                                                                                              Northing (mN); refer to Table AC-1 below. 
                      *    Quality and adequacy of topographic control. 
 
                                                                                         *    The Arya rock chip sample dataset is anticipated on 
                                                                                              average to have up to a +/-20m horizontal level of 
                                                                                              accuracy in sample locations and range up to a +/-10m 
                                                                                              of accuracy in sample locations for vertical 
                                                                                              accuracy. 
 
 
                                                                                        Surface sample and assay data had been prepared 
                                                                                        and compiled into Manifold GIS System and all data 
                                                                                        converted to GDA94-Zone 54. 
               =================================================================  ================================================================= 
 Data spacing 
 and                  *    Data spacing for reporting of Exploration Results.             *    For the Arya surface sampling modelling for copper, 
 distribution                                                                                  the average RMS sample-to-sample spacing was as 
                                                                                               follows: 
                      *    Whether the data spacing, and distribution is 
                           sufficient to establish the degree of geological and 
                           grade continuity appropriate for the Mineral Resource         o Rock chip 200m 
                           and Ore Reserve estimation procedure(s) and                    *    Drillholes were spaced approximately 250m apart. 
                           classifications applied. 
 
 
                      *    Whether sample compositing has been applied. 
               =================================================================  ================================================================= 
 Orientation 
 of data              *    Whether the orientation of sampling achieves unbiased         *    In general, the strike of the Surprise Creek 
 in relation               sampling of possible structures and the extent to                  Formation is east-northeast to east, dipping 
 to                        which this is known, considering the deposit type.                 moderately to the north. 
 geological 
 structure 
                      *    If the relationship between the drilling orientation          *    For 'Arya' rock chips there was no fixed orientation 
                           and the orientation of key mineralised structures is               as these methods were used in the first instance to 
                           considered to have introduced a sampling bias, this                define distinct areas of anomalisms, based on areas 
                           should be assessed and reported if material.                       of observed surface mineralisation. 
 
 
                                                                                         *    For 'Arya' rock chips that produced significant 
                                                                                              anomalous values appear to be associated with the 
                                                                                              mapped fault, fault bounded breccia, and the Surprise 
                                                                                              Creek Formation 'PLrd' rock unit ('Prd' historical) 
                                                                                              that dominates the 'Arya' prospect to the south of 
                                                                                              the fault. 
 
 
                                                                                         *    All drilling is intended to be vertical to intersect 
                                                                                              the dipping sedimentary beds. 
               =================================================================  ================================================================= 
 Sample 
  security             *    The measures taken to ensure sample security.                *    Each day's RC samples were removed from site and 
                                                                                              stored in a secure location off site. 
 
 
                                                                                         *    The RC chip samples taken were securely locked within 
                                                                                              the vehicle on site until delivered to Mt Isa for 
                                                                                              despatch to the laboratory in person by the field 
                                                                                              personnel. 
               =================================================================  ================================================================= 
 Audits                                                                            No external reviews or audits have been undertaken, 
  or reviews           *    The results of any audits or reviews of sampling        except for the Independent Geologists Report by 
                            techniques and data.                                    SRK in 2019 for the LSE Listing and a review of 
                                                                                    the airborne and ground geophysics by the GeoDiscovery 
                                                                                    Group. Note, the reference is: Nelson K., Review 
                                                                                    of open file EM and magnetic geophysical data at 
                                                                                    Arya Prospect, GeoDiscovery Group, unpublished 
                                                                                    confidential report to Castillo Copper Limited, 
                                                                                    June 2021, 16pp. 
               =================================================================  ================================================================= 
 

Drilling program summary

The inaugural drilling campaign at the Arya Prospect (Figure AC-1) was completed in December 2021, after a massive logistical effort to prepare the drill-pads and heli-lift the rig and all supporting equipment to site (see Figure AC-2). In each hole thick horizons (up to 55m) of dark grey and black carbonaceous siltstone / schist were intersected (Figure AC-3), with scattered, sparse base-metal sulphides, low levels of silver and TREO (to 400ppm), and fine-grained graphite mineralisation occurrences which remains open in all directions and to depth.

FIGURE AC-1: PROSPECTS COMPRISING THE NWQ COPPER PROJECT

Source: CCZ geology team

FIGURE AC-2: DRILLING AT SITE AR_20 (AR_001RCR)

Location: 351825 mN; 7865551 Mn; Source: CCZ geology team

The "proof of concept" campaign, which eventually only comprised five initial RC drill-holes at four sites. Delays to the drilling were extensive and have included:

   --    Wet weather and flooding. 
   --    Daytime temperatures >43 degrees Celsius. 
   --    Compressor overheating. 
   --    Drill thread breaking. 
   --    Large water flows in each hole drilled. 
   --    Bushfires. 
   --    Helicopter lifts of all gear required between sites and daily travel to/from site. 
   --    Very hard quartzite wearing down hammer components. 

The key focus was drill-testing the three targets identified by BHP in the mid-1990s including EG01, EG02 and EG10. Of these, EG01 had been interpreted to potentially be a massive sulphide bedrock conductor 130m thick, 1,500m long and 450m wide at a revised 100-200m depth.

Drilling to date has found no sign of massive copper sulphide mineralisation, but instead thick horizons (10-40m) of a dark grey to black carbonaceous, siltstone to schist, exhibiting scattered base metal mineralisation and fine-grained graphite occurrences (Figure AC-3). The horizons are not magnetic, but portable XRF readings, supported by laboratory analyses have identified scattered anomalous chromium, zinc, cobalt, manganese, and rare earth element readings throughout the sequence (Figure AC-4). All 1m samples were collated to 4m composites, then analysed for a comprehensive suite of trace and rare earth elements, total carbon, and total graphitic carbon.

FIGURE AC-3: AR_001RCR CHIP TRAY 111-120m

Source: CCZ geology team

Post reconciling historic geochemical and geophysical data, the Board decided it was strategically more prudent to orchestrate a "proof of concept" reduced campaign comprising five RC drill-holes initially which included sites AR04, AR08, AR09, AR13 & AR21 (Table AC-1 and Figure AC-4). Vertical holes were planned however due to the drilling techniques and narrower diameter pipe employed, several completed drillholes exhibited significant downhole deviations to the south-east and south-west (Figure AC-5).

The exploration program objective was changed so that if the first-round observations and geological findings were encouraging, there is built-in flexibility to expand the campaign to fully drill-test the extent of any underlying system.

Drilling of AR_002RC progressed to a depth of 238m before the drill string disintegrated leaving most of the drill string stuck in the hole. The drillhole had deviated significantly, being almost horizontal at total depth. Drilling in AR_001RCR through to AR_004RC intersected, hard, dark, material identified as a carbonaceous schist (See Appendix B). The material contains no base metal mineralisation, but a low tenor of rare earth elements (to 400ppm TREO) and graphite (0.5 - 2%; refer to Appendix B) that was confirmed by laboratory testing.

TABLE AC-1: DRILLHOLE LOCATION

 
 Drillhole    Easting   Northing   AHD     Total    Azimuth   Dip   Type     Comments 
                                            Depth 
                                                                             Quartzite to 42m, 
                                                                              dark carbonaceous 
                                                                              schist to 90m; 
 AR_001RC     351793    7865526    202.2   96       175       -85   RC        Major fault @90m. 
             ========  =========  ======  =======  ========  ====  =======  =================== 
                                                                             Quartzite then 
                                                                              dark carbonaceous 
                                                                              siltstones and 
 AR_001RCR    351825    7865551    203.4   142      172       -60   RC/PCD    schists to TD 
             ========  =========  ======  =======  ========  ====  =======  =================== 
                                                                             Quartzite then 
                                                                              dark carbonaceous 
                                                                              siltstones and 
 AR_002RC     352735    7865605    191.8   238      170       -17   RC        schists to TD 
             ========  =========  ======  =======  ========  ====  =======  =================== 
                                                                             Quartzite then 
                                                                              dark carbonaceous 
                                                                              siltstones and 
 AR_003RC     352971    7865433    192.5   143      203       -60   RC        schists to TD 
             ========  =========  ======  =======  ========  ====  =======  =================== 
                                                                             Quartzite then 
                                                                              dark carbonaceous 
                                                                              siltstones and 
 AR_004RC     353486    7865310    188     177      160       -67   RC        schists to TD 
             ========  =========  ======  =======  ========  ====  =======  =================== 
 

Notes: Coordinate system is MGA94-Zone 54, collars are AHD.

Section 2 Reporting of Exploration Results

(Criteria listed in the preceding section also apply to this section.)

 
 Criteria         JORC Code explanation                                              Commentary 
 Mineral 
  tenement               *    Type, reference name/number, location and ownership           *    The following mineral tenures are held 100% by 
  and land                    including agreements or material issues with third                 subsidiaries of Castillo Copper Limited, totalling an 
  tenure status               parties such as joint ventures, partnerships,                      area of approximately 961km(2) in the "NWQ project": 
                              overriding royalties, native title interests, 
                              historical sites, wilderness or national park and 
                              environmental settings.                                       *    EPM 26574 (Valparaisa North) - encompasses the Big 
                                                                                                 One historical mineral resource, Holder Total 
                                                                                                 Minerals Pty Ltd, granted 12-June-2018 for a 5-year 
                         *    The security of the tenure held at the time of                     period over 100 sub-blocks (323.3Km2), Expires 
                              reporting along with any known impediments to                      11-June-2023. 
                              obtaining a licence to operate in the area. 
 
                                                                                            *    EPM 26462 (Big Oxide North) - encompasses the 
                                                                                                 'Boomerang' historical mine and the 'Big One' 
                                                                                                 historical mine, Holder: QLD Commodities Pty Ltd, 
                                                                                                 granted: 29-Aug-2017 for a 5-year period over 67 
                                                                                                 sub-blocks (216.5Km(2) ), Expires: 28-Aug-2022. 
 
 
                                                                                            *    EPM 26525 (Hill of Grace) - encompasses the Arya 
                                                                                                 significant aeromagnetic anomaly, Holder: Total 
                                                                                                 Minerals Pty Ltd for a 5-year period over 38 
                                                                                                 sub-blocks (128.8Km2), Granted: 12-June 2018, 
                                                                                                 Expires: 11-June-2023. 
 
 
                                                                                            *    EPM 26513 (Torpedo Creek/Alpha Project) - Granted 
                                                                                                 13-Aug 2018 for a 5-year period over 23 sub-blocks 
                                                                                                 (74.2Km2), Expires 12-Aug-2023; and 
 
 
                                                                                            *    EPM 27440 (The Wall) - An application was lodged on 
                                                                                                 the 12-Dec2019 over 70 sub-blocks (215Km(2) ) by 
                                                                                                 Castillo Copper Limited. The tenure was granted on 
                                                                                                 the 7(th) of March 2021. 
                 =================================================================  ============================================================================= 
 Exploration 
  done by other          *    Acknowledgment and appraisal of exploration by other          *    A selection of historical QDEX / mineral exploration 
  parties                     parties.                                                           reports has been reviewed for historical tenures that 
                                                                                                 cover or partially cover the Project Area in this 
                                                                                                 announcement. Federal and State Government reports 
                                                                                                 supplement the historical mineral exploration 
                                                                                                 reporting (QDEX open file exploration records). 
 
 
                                                                                            *    Most explorers were searching for Cu-Au-U and/or 
                                                                                                 Pb-Zn-Ag, and, proving satellite deposit style 
                                                                                                 extensions to the several small sub-economic copper 
                                                                                                 deposits (e.g., Big Oxide and Josephine). 
 
 
                                                                                            *    With the NWQ Project in regional proximity to Mt Isa 
                                                                                                 and numerous historical and active mines, the Project 
                                                                                                 area has seen the historical mineral tenures subject 
                                                                                                 to various styles of surface sampling, with selected 
                                                                                                 locations typically targeted at specific locations 
                                                                                                 within the NWQ Pillar by shallow drilling (Total hole 
                                                                                                 depth is typically less than 75m). 
 
 
                                                                                            *    The NWQ project tenure package has a significant 
                                                                                                 opportunity to be reviewed and explored by modern 
                                                                                                 exploration methods in a coherent package of EPM's, 
                                                                                                 with three of these forming a contiguous tenure 
                                                                                                 package. 
 
 
                                                                                           Arya prospect - the five (5) historical exploration 
                                                                                           reports generated by various explorers that contributed 
                                                                                           information and data to this ASX Release are detailed 
                                                                                           in the References section of the main body. 
                 =================================================================  ============================================================================= 
 Geology 
                         *    Deposit type, geological setting, and style of                           *    The NWQ project is located within the Mt Isa Inlier 
                              mineralisation.                                                               of western Queensland, a large, exposed section of 
                                                                                                            Proterozoic (2.5 billion- to 540-million-year-old) 
                                                                                                            crustal rocks. The inlier records a long history of 
                                                                                                            tectonic evolution, now thought to be like that of 
                                                                                                            the Broken Hill Block in western New South Wales. 
 
 
                                                                                                       *    The NWQ project lies within the Mt Oxide Domain, 
                                                                                                            straddling the Lawn Hill Platform and Leichhardt 
                                                                                                            River Fault Trough. The geology of the tenement is 
                                                                                                            principally comprised of rocks of the Surprise Creek 
                                                                                                            and Quilalar Formations which include feldspathic 
                                                                                                            quartzites, conglomerates, arkosic grits, shales, 
                                                                                                            siltstones and minor dolomites and limestones. 
 
 
                                                                                                       *    The NWQ Pillar project area is cut by a major fault 
                                                                                                            zone, trending north-northeast to south-southwest 
                                                                                                            across the permits. This fault is associated with 
                                                                                                            major folding, forming several tight syncline and 
                                                                                                            anticline structures along its length. 
 
 
                                                                                                       *    The desktop studies commissioned by CCZ on the 
                                                                                                            granted mineral tenures described four main styles of 
                                                                                                            mineralisation account for most mineral resources 
                                                                                                            within the rocks of the Mt Isa Province (after 
                                                                                                            Withnall & Cranfield, 2013). 
 
 
                                                                                                       *    Sediment hosted silver-lead-zinc - occurs mainly 
                                                                                                            within fine grained sedimentary rocks of the Isa 
                                                                                                            Super basin within the 
 
 
                                                                                                       *    Western Fold Belt. Deposits include Black Star (Mount 
                                                                                                            Isa PbZn), Century, George Fisher North, George 
                                                                                                            Fisher South (Hilton) and Lady Loretta deposits. 
 
 
                                                                                                       *    Brecciated sediment hosted copper - occurs dominantly 
                                                                                                            within the Leichhardt, Calvert, and Isa Super basin 
                                                                                                            of the Western Fold Belt, hosted in brecciated 
                                                                                                            dolomitic, carbonaceous, and pyritic sediments or 
                                                                                                            brecciated rocks proximal to major fault/shear zones. 
                                                                                                            Includes the Mount Isa copper orebodies and the 
                                                                                                            Esperanza/Mammoth mineralisation. 
 
 
                                                                                                       *    Iron-oxide-copper-gold ("IOCG") - predominantly 
                                                                                                            chalcopyrite, pyrite magnetite/hematite 
                                                                                                            mineralisation within high grade metamorphic rocks of 
                                                                                                            the Eastern Fold Belt. Deposits of this style include 
                                                                                                            Ernest Henry, Osborne, and Selwyn; and 
 
 
                                                                                                       *    Broken Hill type silver-lead-zinc - occur within the 
                                                                                                            high-grade metamorphic rocks of the Eastern Fold 
                                                                                                            Belt. Cannington is the major example, but several 
                                                                                                            smaller currently sub-economic deposits are known. 
 
 
                                                                                                       *    Gold is primarily found associated with copper within 
                                                                                                            the IOCG deposits of the Eastern Fold Belt. However, 
                                                                                                            a significant exception is noted at Tick Hill where 
                                                                                                            high grade gold mineralisation was produced, between 
                                                                                                            1991 and 1995 by Carpentaria Gold Pty Ltd, some 700 
                                                                                                            000 tonnes of ore was mined at an average grade of 
                                                                                                            22.5 g/t Au, producing 15 900 kg Au. The Tick Hill 
                                                                                                            deposit style is poorly understood (Withnall & 
                                                                                                            Cranfield, 2013). 
 
 
                                                                                                       *    ROM Resources had noted in a series of recent reports 
                                                                                                            for CCZ on the granted tenures, that cover the known 
                                                                                                            mineralisation styles including: 
 
 
                                                                                                      o Stratabound copper mineralisation within ferruginous 
                                                                                                      sandstones and siltstones of the Surprise Creek Formation. 
                                                                                                      o Disseminated copper associated with trachyte dykes. 
                                                                                                      o Copper-rich iron stones (possible IOCG) in E-W 
                                                                                                      fault zones; and 
                                                                                                      o possible Mississippi Valley Type ("MVT") stockwork 
                                                                                                      sulphide mineralisation carrying anomalous copper-lead-zinc 
                                                                                                      and silver. 
                                                                                                       *    The Mt Oxide and Mt Gordon occurrences are thought to 
                                                                                                            be breccia and replacement zones with interconnecting 
                                                                                                            faults. The Mt Gordon/Mammoth deposit is hosted by 
                                                                                                            brittle quartzites, and Esperanza by carbonaceous 
                                                                                                            shales. Mineralisation has been related to the Isan 
                                                                                                            Orogeny (1,590 - 1,500 Ma). 
 
 
                                                                                                       *    Mineralisation at all deposits is primarily 
                                                                                                            chalcopyrite-pyrite-chalcocite, typically as massive 
                                                                                                            sulphide within breccias. 
 
 
                                                                                                       *    At the Big One prospect, West Australian Metals NL 
                                                                                                            described the mineralisation as (as sourced from the 
                                                                                                            document "West Australian Metals NL, 1994. Drill 
                                                                                                            Programme at the "Big One" Copper Deposit, North 
                                                                                                            Queensland for West Australian Metals NL."): 
 
 
                                                                                                       *    The targeted lode / mineralised dyke is observable on 
                                                                                                            the surface. The mineralisation targeted in the 1993 
                                                                                                            drilling programmed is a supergene copper 
                                                                                                            mineralisation that includes malachite, azurite, 
                                                                                                            cuprite, and tenorite, all associated with a NE 
                                                                                                            trending fault (062(o) to 242(o) ) that is intruded 
                                                                                                            by a porphyry dyke. 
 
 
                                                                                                       *    The mineralised porphyry dyke is vertical to near 
                                                                                                            vertical (85(o) ), with the 'true width' dimensions 
                                                                                                            reaching up to 7m at surface. o At least 600m in 
                                                                                                            strike length, with strong Malachite staining 
                                                                                                            observed along the entire strike length, with 
                                                                                                            historical open pits having targeted approximately 
                                                                                                            200m of this strike. Exact depth of mining below the 
                                                                                                            original ground surface is not clear in the 
                                                                                                            historical documents, given the pits are not battered 
                                                                                                            it is anticipated that excavations have reached 5m to 
                                                                                                            10m beneath the original ground surface. 
 
 
                                                                                                       *    Associated with the porphyry dyke are zones of 
                                                                                                            fractured and/or sheared rock, the siltstones are 
                                                                                                            described as brecciated, and sandstones around the 
                                                                                                            shear as carbonaceous. 
 
 
                                                                                                       *    The known mineralisation from the exploration 
                                                                                                            activities to date had identified shallow supergene 
                                                                                                            mineralisation, with a few drillholes targeting 
                                                                                                            deeper mineralisation in and around the 200m of 
                                                                                                            strike historical open A strongly altered hanging 
                                                                                                            wall that contained malachite and cuprite nodules. 
                                                                                                            Chalcocite mineralization has been identified but it 
                                                                                                            is unclear on the prevalence of the Chalcocite; and 
                                                                                                            the mineralisation was amenable to high grade open 
                                                                                                            pit mining methods of the oxide mineralization (as 
                                                                                                            indicated by numerous historical open pit shallow 
                                                                                                            workings into the shear zone). 
 
 
                                                                                                       *    Desktop studies commissioned by CCZ and completed by 
                                                                                                            ROM Resources and SRK Exploration have determined 
                                                                                                            that the Big One prospect is prospective for Cuco, 
                                                                                                            and Ag. 
 
 
                                                                                                       *    Desktop studies commissioned by CCZ have determined 
                                                                                                            the Boomerang prospect contains: 
 
 
                                                                                                       *    Secondary copper staining over 800m of strike 
                                                                                                            length. 
 
 
                                                                                                       *    Associated with a major east-west trending fault that 
                                                                                                            juxtaposes the upper Surprise Creek Formation 
                                                                                                            sediments against both the underlying Bigie Formation 
                                                                                                            and the upper Quilalar Formation units. 
 
 
                                                                                                       *    At the 'Flapjack' prospect there is the potential 
                                                                                                            for: 
 
 
                                                                                                      o Skarn mineralisation for Cu-Au and/or Zn-Pb-Cu 
                                                                                                      from replacement carbonate mineralisation, particularly 
                                                                                                      the Quilalar Formation. 
                                                                                                      o Thermal Gold Auroele mineralisation is a potential 
                                                                                                      model due to the high silica alteration in thermal 
                                                                                                      aureole with contact of A-Type Weberra Granite - 
                                                                                                      related to the Au mineralisation; and/or 
                                                                                                      o IOCG mineralisation related to chloride-rich fluids. 
                                                                                                       *    At the 'Crescent' prospect there is the potential 
                                                                                                            for: 
 
 
                                                                                                      o Skarn mineralisation for Cu-Au and/or Zn-Pb-Cu 
                                                                                                      from replacement carbonate mineralisation, particularly 
                                                                                                      the Quilalar Formation; and/or 
                                                                                                      o Thermal Gold Auroele mineralisation is a potential 
                                                                                                      model due to the high silica alteration in thermal 
                                                                                                      aureole with contact of A-Type Weberra Granite - 
                                                                                                      related to the Au mineralisation; and 
                                                                                                      o IOCG mineralisation related to potassic rich fluids. 
                                                                                                       *    At the 'Arya' prospect there is the potential for: 
 
 
                                                                                                      o Supergene mineralisation forming at the surface 
                                                                                                      along the fault, fault breccia, and the Surprise 
                                                                                                      Creek Formation 'PLrd' rock unit ('Prd' historical). 
                                                                                                      o Epigenetic replacement mineralisation for Cu (with 
                                                                                                      minor components of other base metals and gold) from 
                                                                                                      replacement carbonate mineralisation, particularly 
                                                                                                      the Surprise Creek Formation. 
                                                                                                      o Skarn mineralisation for Cu-Au and/or Zn-Pb-Cu 
                                                                                                      from replacement carbonate mineralisation, particularly 
                                                                                                      the Surprised Creek Formation; and/or 
                                                                                                      o IOCG mineralisation related to chloride rich fluids. 
                                                                                                      A selection of publicly available QDEX documents 
                                                                                                      / historical exploration reports have been reviewed, 
                                                                                                      refer to Section 2, sub-section "Further Work" for 
                                                                                                      both actions in progress and proposed future actions. 
                 =================================================================  ============================================================================= 
 Drill hole 
  Information            *    A summary of all information material to the                  *    There is no historical drilling at Arya. 
                              understanding of the exploration results including a 
                              tabulation of the following information for all 
                              Material drill holes:                                         *    For the 2021 program, all drillhole information was 
                                                                                                 coded to the same formatted spreadsheets used by CCZ, 
                                                                                                 using the LogCheck field software. 
                        o easting and northing of the drill 
                        hole collar 
                        o elevation or RL (Reduced Level -                                  *    For CCZ's current drilling program, this information 
                        elevation above sea level in metres)                                     has been recorded in formatted spreadsheets during 
                        of the drill hole collar                                                 the drilling and will be checked and verified at the 
                        o dip and azimuth of the hole                                            conclusion of the current program. 
                        o down hole length and interception 
                        depth 
                        o hole length.                                                      *    A summary of the holes drilled are given in Table 
                         *    If the exclusion of this information is justified on               AC-1 in Section 1 of Appendix C, above. 
                              the basis that the information is not Material and 
                              this exclusion does not detract from the 
                              understanding of the report, the Competent Person 
                              should clearly explain why this is the case. 
                 =================================================================  ============================================================================= 
 Data 
 aggregation            *    In reporting Exploration Results, weighting averaging          *    No data aggregation methods are utilised in the 
 methods                     techniques, maximum and/or minimum grade truncations                current ASX Release, since the sampling types are 
                             (e.g. cutting of high grades) and cut-off grades are                surface rock chip samples. 
                             usually Material and should be stated. 
 
 
                        *    Where aggregate intercepts incorporate short lengths 
                             of high-grade results and longer lengths of low-grade 
                             results, the procedure used for such aggregation 
                             should be stated and some typical examples of such 
                             aggregations should be shown in detail. 
 
 
                        *    The assumptions used for any reporting of metal 
                             equivalent values should be clearly stated. 
                 =================================================================  ============================================================================= 
 Relationship 
 between                *    These relationships are particularly important in the          *    The strike of the country rock is northeast to east, 
 mineralisation              reporting of Exploration Results.                                   with the deep Arya conductor is orientated east - 
 widths and                                                                                      west. The smaller, shallower conductors strike 
 intercept                                                                                       north-northeast to northeast. The main faulting 
 lengths                *    If the geometry of the mineralisation with respect to               trends is northeast. 
                             the drill hole angle is known, its nature should be 
                             reported. 
                                                                                            *    When available, all mineralised intervals (i.e., 
                                                                                                 >500ppm) will be reported in future ASX releases as 
                        *    If it is not known and only the down hole lengths are               the "as-intersected" apparent thickness (in metres) 
                             reported, there should be a clear statement to this                 and given that all drillholes dip at -90 degrees from 
                             effect (eg 'down hole length, true width not known').               the horizontal, true intersection widths will be 
                                                                                                 calculated during the block modelling process. 
                 =================================================================  ============================================================================= 
 Diagrams 
                         *    Appropriate maps and sections (with scales) and               *    This part will be done once CCZ's current drilling 
                              tabulations of intercepts should be included for any               program is completed, and all samples have been 
                              significant discovery being reported These should                  assayed and verified. 
                              include, but not be limited to a plan view of drill 
                              hole collar locations and appropriate sectional 
                              views.                                                        *    Appropriate diagrams are presented in the body and 
                                                                                                 the Appendices of the current ASX Release. Where 
                                                                                                 scales are absent from the diagram, grids have been 
                                                                                                 included and clearly labelled to act as a scale for 
                                                                                                 distance. 
 
 
                                                                                            *    Maps and Plans presented in the current ASX Release 
                                                                                                 are in MGA94 Zone 54, Eastings (mN), and Northing 
                                                                                                 (mN), unless clearly labelled otherwise. 
                 =================================================================  ============================================================================= 
 Balanced 
  reporting              *    Where comprehensive reporting of all Exploration              *    Comprehensive reporting was completed (Biggs 2022) 
                              Results is not practicable, representative reporting               once CCZ's drilling program had all sample queries 
                              of both low and high grades and/or widths should be                returned and have been verified. 
                              practiced to avoid misleading reporting of 
                              Exploration Results. 
                                                                                           o Appropriate diagrams are presented in the body 
                                                                                           and the Appendices of the current ASX Release (see 
                                                                                           Figure AC-5 and AC-6). Where scales are absent from 
                                                                                           the diagram, grids have been included and clearly 
                                                                                           labelled to act as a scale for distance. 
                                                                                            *    A complete comparison of visual mineralisation 
                                                                                                 estimated by the site geologist will be published 
                                                                                                 once all assays are returned. All intersected 
                                                                                                 intervals are apparent thicknesses in metres. 
                 =================================================================  ============================================================================= 
 Other                                                                                    GEOTEM & PROTEM: 
 substantive            *    Other exploration data, if meaningful and material,            *    The airborne electromagnetic GEOTEM geophysical 
 exploration                 should be reported including (but not limited to):                  survey undertaken by BHP Minerals in 1997 on 
 data                        geological observations; geophysical survey results;                historical tenure EPM11383 & EPM1152. A total of 
                             geochemical survey results; bulk samples - size and                 726-line kilometres were flown on a SE-NW, flown by 
                             method of treatment; metallurgical test results; bulk               'Geoterrex-Dighem Pty Limited' at a mean height of 
                             density, groundwater, geotechnical and rock                         approximately 105m above the ground surface (line 
                             characteristics; potential deleterious or                           spacing 500m apart). Previous interpretations the 
                             contaminating substances.                                           penetration of the GEOTEM method to have an estimated 
                                                                                                 range of between 200-300m below the ground surface, 
                                                                                                 this is dependent on conductivity contrasts, size, 
                                                                                                 and attitude of the subsurface targets. Eleven (11) 
                                                                                                 anomalies were identified, with four (4) recommended 
                                                                                                 for follow up, with three (3) of the four (4) 
                                                                                                 anomalies followed up by ground geophysical at what 
                                                                                                 CCZ calls the 'Arya' prospect. The BHP Minerals 1997 
                                                                                                 GEOTEM survey information was extracted from QDEX 
                                                                                                 Data to accompany the QDEX report information. 
 
 
                                                                                            *    The 'Arya' prospect anomalies are EG01, EG02, EG10, 
                                                                                                 with the geophysical observations of the body and 
                                                                                                 Appendices of the current ASX Release, including the 
                                                                                                 PROTEM observations. The PROTEM observations are 
                                                                                                 anticipated to have a deeper penetration than the 
                                                                                                 GEOTEM observations, based on the PROTEM loop, survey 
                                                                                                 traverse, and/or depth sounding method applied. 
 
 
                                                                                           QUESTEM & GENIE-EM: 
                                                                                            *    The airborne electromagnetic GEOTEM geophysical 
                                                                                                 survey undertaken by Mount Isa Mines in 1991 on 
                                                                                                 historical tenure EPM7448, EPM7338, and EPM7863. A 
                                                                                                 total of approximately 600km-line kilometres (exact 
                                                                                                 line length would need to be extracted from digitised 
                                                                                                 images) would were flown on a SE-NW, flown by 
                                                                                                 'Aerodata Holdings Limited' at a mean height of 
                                                                                                 approximately 120m above the ground surface (line 
                                                                                                 spacing 400m apart). In a previous ASX release (July 
                                                                                                 2020) Xplore Resources Pty Ltd interprets the 
                                                                                                 penetration of the QUESTEM method to have an 
                                                                                                 estimated range of between 200-300m below the ground 
                                                                                                 surface, this is dependent on conductivity contrasts, 
                                                                                                 size, and attitude of the subsurface targets. 
                                                                                                 Twentynine (29) anomalies were identified across the 
                                                                                                 three (3) historical tenure, with six (6) recommended 
                                                                                                 for follow up ground geophysical survey for 
                                                                                                 historical tenure EPM7448, and one of these L4 near 
                                                                                                 the Arya prospect. 
 
 
                                                                                            *    Arya prospect anomaly L4 followed up by a ground 
                                                                                                 electromagnetic traverse by Mount Isa Mines GENIE-EM 
                                                                                                 is to the west of the EG02 BHP minerals anomaly. 
 
 
                                                                                            *    Queensland Government Data: 'PLrd' rock unit lower 
                                                                                                 boundary from the Surprise Creek Formation sourced 
                                                                                                 from QSpatial and aligns with GeoResGlobe - this is 
                                                                                                 equivalent to the historical tenure reports 'Prd' 
                                                                                                 rock unit lower boundary from the Surprise Creek 
                                                                                                 Formation. 
 
 
                                                                                           GEODISCOVERY REVIEW 
                                                                                           The study of Nelson (2021) concluded that: 
                                                                                            *    Whilst hard copies of the 1997 BHP ground EM data are 
                                                                                                 available, no digital data is on open file. Hard copy 
                                                                                                 profiles have been visually interpreted, however due 
                                                                                                 to lack of digital data it cannot be remodelled. The 
                                                                                                 historic BHP model results and survey locations have 
                                                                                                 not been provided and there is uncertainty in the 
                                                                                                 location of Anomaly E02. 
 
 
                                                                                            *    Magnetic modelling, CDI and LEI of the TEMPEST survey 
                                                                                                 line indicate the BHP depth estimate of conductive 
                                                                                                 from the EG01 sounding is likely over estimated. 
                                                                                                 Depth to main conductive sources appears to be 
                                                                                                 between around 200m beneath surface (Nelson (2021). 
 
 
                                                                                            *    EG02 appears to be associated with a fault and EG10 
                                                                                                 appears to be more surficial. 
 
 
                                                                                            *    It is recommended that the LEI of the TEMPEST survey 
                                                                                                 (most recent AEM data acquired in the region), along 
                                                                                                 with magnetic model output be used to plan the next 
                                                                                                 drill campaign. The current drill plan could be 
                                                                                                 improved to better test the modelled conductive 
                                                                                                 sources and structural features. 
 
 
                                                                                            *    If the drill testing of the conductive sources 
                                                                                                 indicates the presence of prospective lithologies 
                                                                                                 and/or mineralisation, then consideration should be 
                                                                                                 given to acquiring detailed ground EM and magnetic 
                                                                                                 coverage to further assist targeting. 
                 =================================================================  ============================================================================= 
 Further 
  work                   *    The nature and scale of planned further work (eg                          *    Further work will consist of a combination of: 
                              tests for lateral extensions or depth extensions or 
                              large-scale step-out drilling). 
                                                                                                       o Fourteen (14) hole RC drilling Program 
                                                                                                       o Soil and or Rock chip sampling 
                         *    Diagrams clearly highlighting the areas of possible                      o Ground IP or EM Survey 
                              extensions, including the main geological 
                              interpretations and future drilling areas, provided 
                              this information is not commercially sensitive. 
                 =================================================================  ============================================================================= 
 

FIGURE AC-4: ARYA DRILLHOLE LOCATION vs EM ANOMALY

Notes:

   1.        Coordinate system is MGA94-Zone 54, collars are AHD. 

2. Shows EM anomalies, MIM EM airborne survey, Location of AusAEM survey line 2024_003, and the "as drilled" 2021 collars.

FIGURE AC-5: ARYA DRILLHOLE LOCATION AND GRAPHITE INTERSECTIONS

Notes:

   1.        View at Ayra looking north-east, showing topography (2m contours) and drilling. 
   2.        Coloured bars represent Cg >0.5%, with purple higher grade (>1% TGC). 

3. Light green polygons (see Figure AC-4) present surface copper anomalies (>250ppm Cu) untested by drilling.

   4.        Source: CCZ Geology Team. 

References

Anaconda Australia Inc., 1971. Authority to Prospect 791M "Myally", Queensland. Final Report. QDEX Report number: 3544.

Biggs M.S., 2021, EPM 26525 Hill of Grace - 2021 Arya Drilling and Exploration Program, End of Hitch Report - Drilling, Assay, and Metallurgical Testing Completed, July 2022, unpublished report by ROM Resources for Castillo Copper Limited.

BHP Minerals Pty Ltd, 1997. EPM 11383 (Alsace Camp), 11452 (Epsilon), Combined Annual Report for the Period Ending 19/12/97. QDEX Report number: 29762.

BHP Minerals Pty Ltd, 1998. EPM 11383 (Alsace Camp), 11452 (Epsilon), Combined Annual/Final Report for the Period Ending 19/12/98. QDEX Report number: 30750

CCZ ASX Release - 28 April 2020.

CRA Exploration Pty Limited, 1995. Exploration Report for Minerals No. 9575 "Epsilon", Queensland. Annual Report for the period ended August 3, 1995. QDEX Report number: 27102.

CRA Exploration Pty Limited, 1996. Exploration Report for Minerals No. 9575 "Epsilon", Queensland. Third Annual and Final Report for the Period Ending 2 July 1996. QDEX Report number: 28337

GeoResGlobe, 2021, Detailed Geology 1:100,000 layers. https://georesglobe.information.qld.gov.au/ Accessed 2021-Jun-21.

M.I.M Exploration Pty Ltd, 1992a, Exploration Permit for Minerals No. 7863 "Eldorado" Queensland. Annual Report for the 12 months ended April 17, 1992. QDEX Report number: 23661.

M.I.M Exploration Pty Ltd, 1992b "Myally Creek" EPM 7338 and "Lagoon Creek" EPM 7448 Joint Twelve Month Report for Period 18 May 1990 to 18 May 1991 Queensland, Australia. QDEX Report number: 23516.

Mt Isa Metals Ltd, 2010. EPM 15767, Myally Tenement, Annual Report for the Period 5/06/2009 to 4/6/2010. QDEX Report number: 64491.

M.I.M Exploration Pty Ltd, 1993. Exploration Permit for Minerals Nos. 7448 "Lagoon Creek". Second Annual Report 18 May 1991 to 17 May 1992, Queensland Australia. QDEX Report number: 24523.

Nelson K., 2021, Review of open file EM and magnetic geophysical data at Arya Prospect, GeoDiscovery Group, unpublished confidential report to Castillo Copper Limited, June 2021, 16pp

Pacminex Pty Limited, 1975, Authority to Prospect No. 1494M "Alsace Area", Queensland. Annual Report. QDEX Report number: 5602.

Queensland Government, 2021. Queensland Geology Detailed Web Map Service: http://qldspatial.information.qld.gov.au/catalogue/custom/search.page?q=solid+geology#

Schulz, M., Liu, J., and de Nooy, D., 2022, MIN5684 (A23397), Castillo Copper Ltd, Graphite Optical Analysis, ALS Metallurgical Services, May 2022, 18pp

Valenta, R., 2018. NW Queensland Mineral Province Deposit Atlas Prototype Report - the Mount Isa and Ernest Henry Deposits. DNRME-GSQ Commissioned study and report.

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